Uncovered fiberglass insulation is dangerous to breathe

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006 (REACH), Annex II - Austria1.SAFETY DATA SHEETIDENTIFICATION OF THE SUBSTANCE OR THE PREPARATION AND THE COMPANY Product name and / or code Manufacturer / dealer :: ISOMAT WVISOMAT WVAkzo Nobel Coatings GmbH, Aubergstrasse 7, A-5161 Elixhausen, Austria Tel .: +43 662 489890, Fax .: +43 662 48989-11, Internet: www.herbol .atE-mail address of the person responsible for this SDSUse of the productEmergency number (with operating times): [email protected]: Aqueous coating agent for outside Hours / day, every day) 2. HAZARDS IDENTIFICATION The product is classified as dangerous according to Directive 1999/45 / EC and its amendments.Classification: R52 / 53Danger to the environment3 .: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.COMPOSITION / INFORMATION ON INGREDIENTS Substances that represent a health or environmental hazard in accordance with the interpretation of the Hazardous Substances Directive 67/548 / EEC or to which an occupational exposure limit has been assigned calculation CAS number% number Classification Quartz (SiO2) 14808-60-7 1 - 2.5 238-878-4 Xn; R48 / 20 [1] [2] zinc oxide 1314-13-2 1 - 2.5 215-222-5 N; R50 / 53 [1] ammonia, anhydrous 7664-41-7 0 - 1 231-635-3 R10T; R23C; R34N; R50 [1] [2] See Section 16 for the full wording of the R-phrases declared above There are no additional ingredients which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and therefore require reporting in this section. [1] Substance classified as hazardous to health or the environment [2] Substance with an occupational exposure limit value [3] PBT substance [4] vPvB substanceThe limit values ​​for exposure at the workplace are listed in section 8, if available. Date of issue / Date of revision: 22-11-2009 . Page: 1/10


ISOMAT WV4.FIRST AID MEASURESFirst Aid MeasuresGeneral InhalationSkin ContactEye Contact Ingestion ::::: If symptoms occur or in any case of doubt, consult a doctor. Never give anything by mouth to an unconscious person. In the event of unconsciousness, lay on your side and seek medical advice. Remove to fresh air. Keep person warm and calm. If breathing is absent or irregular, or if breathing has stopped, well-trained personnel must be given artificial respiration or oxygen. Remove contaminated clothing and shoes. Use skin thoroughly with soap and water or approved skin cleanser. Do not use solvents or thinners. Check for contact lenses and remove if present. Immediately flush eyes with running water for at least 15 minutes, holding the eyelids open. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and calm. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Extinguishing media not to be used Recommended: alcohol-resistant foam, CO2, powder, water spray .: Do not use water jet.Special exposure hazards: Fire produces thick black smoke. The effects of the decomposition products can be detrimental to health. Suitable respiratory protection may be required. Cool fire-exposed containers with water. Do not allow extinguishing water to enter drains or waterways. 6. ACCIDENTAL RELEASE MEASURES Due to the content of organic solvents: Personal precautionary measuresEnvironmental protection measuresCleaning methods: Keep away sources of ignition and ventilate the room well. Avoid breathing vapor or mist. Observe protective regulations in sections 7 and 8. Contain leaked material with non-flammable absorbent material (e.g. sand, earth, vermiculite, kieselguhr) and place in a container provided for disposal in accordance with local regulations (see Section 13) .: Do not allow to enter drains or bodies of water. If rivers, lakes or sewers are contaminated, inform the relevant authorities in accordance with local laws. Avoid the use of solvents. Note: See Section 8 for personal protective equipment and Section 13 for information on waste disposal. 7. HANDLING AND STORAGE Handling: Due to the content of organic solvents: Vapors are heavier than air and can spread along the ground. Vapors can combine with air form an explosive mixture. Avoid the formation of flammable and explosive solvent vapors in the air and avoidance of the workplace limit values. Only use the product in places where there are no open flames and other sources of ignition. Protect electrical devices in accordance with the relevant standards. Keep container tightly closed. Keep away from heat, sparks and flames. Do not use tools that generate sparks and avoid contact with skin and eyes. Avoid breathing dust, particles, spray mist or mist resulting from the use of this preparation. Do not inhale grinding dust. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Date of issue / Date of revision: 22-11-2009. Page: 2/10


ISOMAT WV7.HANDLING AND STORAGE Put on suitable personal protective equipment (see Section 8). Never empty with pressure. The container is not a pressure vessel. Always store in containers made of the same material as the original container. Follow the legal protection and safety regulations. If people, regardless of whether they are spraying themselves or not, are inside the spray booth during painting, is affected of aerosols and solvent vapors to be expected. In such conditions, respiratory protection should be worn during spray painting until the aerosol and solvent vapor concentration has fallen below airborne limits. Storage: Store in accordance with local regulations. Follow the instructions on the label. Store in a dry, cool and well-ventilated place. Keep away from heat and direct sunlight.Due to the content of organic solvents: Keep away from sources of ignition. Keep away from: oxidizing agents, strong alkalis, strong acids. Prevent unauthorized entry. Closely reseal containers that have been opened and store upright to prevent leakage. 8. LIMITATION AND MONITORING OF EXPOSURE / PERSONAL PROTECTIVE EQUIPMENTName of the ingredientLimitation and monitoring of exposure at the workplaceRespiratory organs: Skin and bodyHandsEyes :: Occupational exposure limits Quartz (SiO2) GKV_MAK (Austria, 9/2007) .AMV: 0.15 mg / m³ 1 hour (s). Form: dust, alveolar fraction of ammonia, anhydrous GKV_MAK (Austria, 9/2007) .MAK - short-term values: 36 mg / m³, 4 times per shift, 15 minute (s) .MAK - short-term values: 50 ppm, 4 times per shift, 15 minutes (n) .MAK - daily mean value: 14 mg / m³, 4 times per shift, 8 hour (s) .MAK - daily mean value: 20 ppm, 4 times per shift, 8 hour (s). Limitation and monitoring of exposure Limiting and monitoring of environmental exposure: For sufficient Provide ventilation. Where reasonably practicable, this can be done through local suction and good general ventilation. If this is insufficient to keep the particle and solvent vapor concentration below the workplace limits, suitable respiratory protection must be worn. If workers are exposed to concentrations above the limit, they must wear suitable and approved breathing apparatus. When dry grinding, cutting flame cutting and / or welding cured paint can produce dangerous dust or smoke. If possible, wet grinding.If exposure to exhaust systems cannot be adequately avoided, appropriate breathing apparatus must be worn.Personnel should wear antistatic clothing made of natural fibers or heat-resistant synthetic fibers.Use suitable protective skin ointment for all uncovered parts of the body; Do not use after exposure has occurred.Wear protective goggles to protect against splashes .: Do not empty into drains or bodies of water. Date of issue / Date of revision: 22-11-2009. Page: 3/10


ISOMAT WV9. PHYSICAL AND CHEMICAL PROPERTIESPhysical stateViscosityRelative density: 1.379Solubility ::: Liquid.Flash point: Not applicable.Kinematic: 11.6 cm 2 / s (1160 cSt) 10. STABILITY AND REACTIVITYConditions to avoidSubstances to avoidDangerous decomposition products11. TOXICOLOGICAL INFORMATION ToxicokineticsResorption: Not available. ::: Easily soluble in the following materials: cold water.Stable under recommended storage and handling conditions (see section 7). May form dangerous decomposition products when exposed to high temperatures.Keep away from the following materials to cause strong exotherms Avoid reactions: oxidizing agents, strong alkalis, strong acids.The decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, nitrogen oxides.Distribution: Contains material which causes damage to the following organs: lungs, cardiovascular system, upper respiratory tract, Eye, lens or cornea.Contains material which may cause damage to the following organs: skin.There is no information available on the preparation itself. The preparation was evaluated according to the conventional method of the Preparation Directive 1999/45 / EC and classified according to its toxicological hazards. See Sections 3 and 15 for details. Exposure to solvent vapors above the occupational exposure limit can lead to health problems, such as irritation of the mucous membranes and respiratory organs and damage to the liver, kidneys and the central nervous system. The signs include: headache, dizziness, tiredness, muscle weakness, drowsiness and, in severe cases, unconsciousness. Solvents can cause some of the above effects when absorbed through the skin. Prolonged or repeated contact with the product may cause degreasing of the skin resulting in non-allergic contact dermatitis and absorption through the skin.Splashes in the eyes may cause irritation and reversible damage.Acute toxicityProduct / ingredient name Result Species Dose Exposure Quartz (SiO2) LDLoRat 250 mg / kg -IntratrachealLDLoRat 200 mg / kg -IntratrachealLDLo Intravenous Rat 90 mg / kg -TDLoRat 100 mg / kg -IntratrachealTDLoRatte 50 mg / kg -IntratrachealTDLoRatte 30 mg / kg -IntratrachealTDLoRatte 25 mg / kg -IntratrachealTDLoRatte 25 mg / kg -IntratrachealTDLoRatte 25 mg / kg -Intratracheal TDLo rat 10 mg / kg -Intratracheal TDLo rat 5 mg / kg -Intratracheal TDLo rat 1.5 mg / kg -Intratracheal TDLo rat 1 mg / kg -Issue date / Revision date: 22-11-2009. Page: 4/10


ISOMAT WV11. TOXICOLOGICAL INFORMATIONIntratrachealTDLoRat 1250 ug / kg -IntratrachealTDLoRatte 150 mg / kg -IntratrachealTDLo Oral Rat 120 g / kg -Zinc oxide LD Intratracheal Rat> 4979 ug / kg -LD Oral Rat> 8437 mg / kg -LD50Rat> 8437 mg / kg -LD50Rat> 8437 mg / kg -LD50Rat Inhalation rat 7040 mg / m3 30 minutes vapor LC50 inhalation rat 18600 mg / m3 5 minutes vapor LC50 inhalation rat 9500 ppm 1 hour gas LC50 inhalation rat 2000 ppm 4 hours gas LC50 inhalation gas rat 17401 ppm 15 minutesConclusion / SummaryChronic toxicityConclusion / ConclusionConclusion / conclusionConclusionoxicity / Summary: Not available .: Not available .: Not available .: Not available .: Not available .: Not available.12. ECOLOGICAL INFORMATION There is no information available on the preparation. Do not empty into drains or bodies of water. The preparation was evaluated according to the conventional method of the Dangerous Preparations Directive 1999/45 / EC and classified according to its ecotoxicological properties. For details see chapters 3 and 15. Aquatic ecotoxicity Name of the product / ingredient Test result Species Zinc oxide - Acute EC50 24.6mg / l Daphnia -Daphnia magna- Acute EC50 0.14 Daphnia -mg / lDaphnia pulex- Acute EC50 0.11 Daphnia -mg / lCeriodaphniadubia poisoning Acute EC50> 1000 Daphnia - Waterppmflea - Daphnia Fresh water magna -


ISOMAT WV12.


ISOMAT WV12. ENVIRONMENTAL ANGABENbis 9640 ug / LMeerwasserSterblichkeit acute LC50 5210bis 6040 ug / LMeerwasserSterblichkeit acute LC50 4980bis 9070 ug / LMeerwasserSterblichkeit acute LC50 4180bis 6030 ug / LFrischwasserSterblichkeit acute LC50 4130bis 5100 ug / LFrischwasserSterblichkeit acute LC50 2710bis 3670 ug / LFrischwasserSterblichkeit acute LC50 2500ug / LFrischwasserSterblichkeit acute LC50 1600bis 1730 ug / LFrischwasserSterblichkeit acute LC50 1550ug / LFrischwasserSterblichkeit acute LC50 660ug / LFrischwasserSterblichkeit acute LC50 450 to 470 ug / LFrischwasserSterblichkeit acute LC50 440ug / LFrischwasserpaulo shrimp -Penaeuspaulensis - PostlarvaeKrustazeen -Redtail prawn -Penaeuspenicillatus -ZoeaKrustazeen -Kuruma shrimp -Penaeusjaponicus -NaupliiDaphnie - Waterflea - Daphniamagna -


ISOMAT WV12. ECOLOGICAL INFORMATIONConclusion / SummaryPersistence / DegradabilityConclusion / SummaryPBTvPvB: Not available .: Not available .: Not applicable .: Not applicable.13. METHOD ENTSORGUNGug / LFrischwasserSterblichkeit acute LC50 300ug / LFrischwasserSterblichkeit acute LC50 16010bis 21460 ug / LMeerwasserSterblichkeit acute LC50 31260ug / L sea water acute mortality LC50 25400ug / LFrischwasserSterblichkeit acute LC50 22790bis 32200 ug / LMeerwasserSterblichkeit acute LC50 14860bis 19140 ug / LMeerwassercarp -Hypophthalmichthysmolitrix -FingerlingFisch - Carp -HypophthalmichthysnobilisKrustazeen -Kuruma shrimp -Penaeusjaponicus - MysisCrustaceans -Redtail prawn -Penaeuspenicillatus - 3.58 to 4.75 cm - 0.4 to 0.69 gDaphnia - Waterflea - DaphniamagnaCrustacea -Kuruma shrimp -Penaeusjaponicus - Postlarvae -prawn48 hours -Rillatus 96 hours Hours 48 hours Do not empty into drains or bodies of water. All relevant federal, state and local regulations must be observed for disposal. Hazardous waste: The classification of the product may meet the criteria for dangerous enWaste. 14. TRANSPORT INFORMATIONTransport on factory premises: only transport in closed containers that are upright and stable.Persons who transport the product must be instructed in the correct behavior in the event of an accident, leakage or spillage.SeaSpecial regulationsMarine pollutantAirSpecial regulations: Not available.:No .: Not available. The "Viscosity Exception" provisions do not apply to air transport. The product is not regulated under ADR / RID, IMDG, ICAO / IATA. Date of issue / Date of revision: 22-11-2009. Page: 8/10


ISOMAT WV15. REGULATORY INFORMATIONEU-RegulationsR-PhrasesS-PhrasesAdditional warning notes (CEPE) National regulationsClassification, packaging and labeling: The product is classified and labeled for delivery according to Directive 1999/45 / EC as follows ::: R52 / 53- Harmful to aquatic organisms, may cause long-term harmful effects in the aquatic environment .S23- Do not breathe vapor or aerosol. S51- Use only in well-ventilated areas. S2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately and show this container or label .: Not applicable. The information in this Safety data sheets are required according to Annex II of Regulation (EC) No. 1907/2006. Restriction of the use of organic solvents: Permitted. 16. OTHER INFORMATIONENCEPE-Classification: 2Full wording of the R-Phrases referred to in Sections 2 and 3 -AustriaDate of issue / Date of revisionVersionNote to reader ::: R10- Flammable.R23- Toxic by inhalation.R48 / 20- Harmful: Risk of serious damage to health by prolonged exposure Inhalation.R34- Causes burns.R50- Very toxic to aquatic organisms.R50 / 53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52 / 53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 22-11-2009.10 For Professional Use Only: Important Note: The information in this data sheet is not intended to be exhaustive in every detail. They are based on the current state of our knowledge and on the currently applicable laws: Anyone who uses the product for any other use than that specified in the technical data sheet, without having previously received written confirmation of the suitability of the product for this purpose from us, acts on his own Danger. It is always the responsibility of the user to take all necessary measures so that the laws and regulations applicable in the area of ​​the user are complied with. The material data sheet and / or the technical data sheet (depending on availability) for this product must be read before use. Any recommendation or explanation made by us about the product (in this data sheet or otherwise) is given according to our current state of knowledge. The quality or condition of the substrate and other factors can influence the use and application of the product.We therefore assume no liability for the performance of the product or for any loss or damage resulting from the use of the product, unless we have expressly given our written consent. All products supplied and technical recommendations given are subject to our standard delivery and payment conditions. Obtain a copy of this document and review it carefully. The information contained in this data sheet is subject to change from time to time based on further experience and in accordance with our guidelines. It is the responsibility of the user to ensure that he has the latest version of this data sheet before using the product. Date of issue / Date of revision: 22-11-2009. Page: 9/10


ISOMAT WV16. OTHER INFORMATION Brand names mentioned in this data sheet are trademarks or licensed for AkzoNobel. Head Office Akzo Nobel Decorative Coatings B.V, Rijksstraatweg 31, 2171 AJ Sassenheim, the Netherlands Date of issue / Date of revision: 22-11-2009. Page: 10/10

According to Regulation (EC) No. 1907/2006 (REACH), Annex II - Austria1. SAFETY DATA SHEET IDENTIFICATION OF THE SUBSTANCE OR THE PREPARATION AND THE COMPANY Product name and / or code Manufacturer / dealer :: ISOMAT WVISOMAT WVAkzo Nobel Coatings GmbH, Aubergstrasse 7, A-5161 Elixhausen, Austria Tel .: +43 662 489890, Fax .: +43 662 48989-11, Internet: www.herbol .atE-mail address of the person responsible for this SDSUse of the productEmergency number (with operating times): [email protected]: Aqueous coating agent for outside Hours / day, every day) 2. HAZARDS IDENTIFICATION The product is classified as dangerous according to Directive 1999/45 / EC and its amendments.Classification: R52 / 53Danger to the environment3 .: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.COMPOSITION / INFORMATION ON INGREDIENTS Substances that represent a health or environmental hazard in accordance with the interpretation of the Hazardous Substances Directive 67/548 / EEC or to which an occupational exposure limit has been assigned calculation CAS number% number Classification Quartz (SiO2) 14808-60-7 1 - 2.5 238-878-4 Xn; R48 / 20 [1] [2] zinc oxide 1314-13-2 1 - 2.5 215-222-5 N; R50 / 53 [1] ammonia, anhydrous 7664-41-7 0 - 1 231-635-3 R10T; R23C; R34N; R50 [1] [2] See Section 16 for the full wording of the R-phrases declared above There are no additional ingredients which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and therefore require reporting in this section. [1] Substance classified as hazardous to health or the environment [2] Substance with an occupational exposure limit value [3] PBT substance [4] vPvB substanceThe limit values ​​for exposure at the workplace are listed in section 8, if available. Date of issue / Date of revision: 22-11-2009 . Page: 1/10